1,2-Thiaborolide:  A New Heteroaromatic π-Ligand Containing Boron and Sulfur Arthur J. Ashe Xiangdong Fang Jeff W. Kampf 10.1021/om000815g.s001 https://acs.figshare.com/articles/journal_contribution/1_2-Thiaborolide_A_New_Heteroaromatic_-Ligand_Containing_Boron_and_Sulfur/3764412 The heteroaromatic anion lithium 2-(diisopropylamino)-1,2-thiaborolide (<b>3</b>) has been prepared by a synthesis using the Grubbs ring-closing metathesis. <b>3</b> has been converted to the Cp*Ru complex <b>10</b>, the Cp*ZrCl<sub>2</sub> complex <b>11</b>, and the Me<sub>2</sub>Si-bridged CpZrCl<sub>2</sub> complex <b>15</b>. 2000-10-28 00:00:00 Containing Ligand heteroaromatic diisopropylamino metathesi New Sulfur Boron lithium CpZrCl synthesis Grubb anion Heteroaromatic Thiaborolide Cp