10.1021/om000406k.s001 Stefan Reinartz Stefan Reinartz Peter S. White Peter S. White Maurice Brookhart Maurice Brookhart Joseph L. Templeton Joseph L. Templeton Tp‘PtH<sub>3</sub>:  A Stable Platinum(IV) Trihydride American Chemical Society 2000 Tp Stable Pt monomeric methanol Si Cleavage trihydride Trihydride precursor Et bond 2000-08-09 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Tp_PtH_sub_3_sub_A_Stable_Platinum_IV_Trihydride/3763038 Tp‘PtMe<sub>2</sub>H (<b>1</b>) reacts with Et<sub>3</sub>Si−H to form Tp‘Pt(SiEt<sub>3</sub>)(H)<sub>2</sub> (<b>2</b>), which serves as a precursor to Tp‘PtH<sub>3</sub> (<b>3</b>). Cleavage of the Pt−SiEt<sub>3</sub> bond of <b>2</b> with methanol provides a clean route to Tp‘PtH<sub>3</sub> (<b>3</b>), a rare N-supported monomeric platinum(IV) trihydride complex.