10.1021/om000089h.s001
K. Rajender Reddy
K. Rajender
Reddy
K. Surekha
K.
Surekha
Gene-Hsiang Lee
Gene-Hsiang
Lee
Shie-Ming Peng
Shie-Ming
Peng
Shiuh-Tzung Liu
Shiuh-Tzung
Liu
Palladium(II) Complexes with Phosphorus−Nitrogen
Mixed Donors. Efficient Catalysts for the Heck Reaction
American Chemical Society
2000
methyl acrylate
phenyl iodide
10 6
sodium iodide
turnover number
catalyst
Heck product
Heck reaction
Efficient Catalysts
NMP
2000-05-12 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Palladium_II_Complexes_with_Phosphorus_Nitrogen_Mixed_Donors_Efficient_Catalysts_for_the_Heck_Reaction/3762066
Pd(II) complexes of phosphine−nitrogen (P−N) bidentate donors act as efficient catalysts for the Heck
reaction. In a typical example, reaction of phenyl iodide
with methyl acrylate in <i>N-</i>methylpyrrolidinone (NMP)
at ca. 130 °C provides the Heck product with a turnover
number of up to 10<sup>6</sup>. In addition, the coupling reaction
of 4-bromoacetophenone with olefin in a quantitative
yield was achieved by using the same catalyst in the
presence of sodium iodide.