10.1021/ol991189q.s001
Hiroshi Furuno
Hiroshi
Furuno
Takeshi Hanamoto
Takeshi
Hanamoto
Yuichi Sugimoto
Yuichi
Sugimoto
Junji Inanaga
Junji
Inanaga
Remarkably High Asymmetric
Amplification in the Chiral Lanthanide
Complex-Catalyzed Hetero-Diels−Alder
Reaction: First Example of the
Nonlinear Effect in ML<sub>3</sub> System
American Chemical Society
1999
homochiral ML 3 complexes
ML 3 System
Remarkably High Asymmetric Amplification
radii
Lanthanide
amplification
Yb
mechanism
Chiral
BNP
Nonlinear Effect
ytterbium ion
catalyst
First
ligand
enantiopure
lanthanide metal ions
autogenetic formation
1999-12-14 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Remarkably_High_Asymmetric_Amplification_in_the_Chiral_Lanthanide_Complex-Catalyzed_Hetero-Diels_Alder_Reaction_First_Example_of_the_Nonlinear_Effect_in_ML_sub_3_sub_System/3761355
A remarkably high asymmetric amplification was realized in the Yb[(<i>R</i>)-BNP]<sub>3</sub>-catalyzed hetero-Diels−Alder reaction as the first example in the
metal/chiral ligand 1:3 system. The mechanism may be explained by the autogenetic formation of the enantiopure complex as the most active
catalyst. The enantiomer-discriminative formation of homochiral ML<sub>3</sub> complexes is quite general within the lanthanide metal ions with similar
ionic radii to that of the ytterbium ion.