Thia-Wittig-like Reactions as a New Route for the Stereoselective Synthesis of (<i>Z</i>)-Fluoroalkenoates David Chevrie Thierry Lequeux Jean-Claude Pommelet 10.1021/ol990178u.s001 https://acs.figshare.com/articles/journal_contribution/Thia-Wittig-like_Reactions_as_a_New_Route_for_the_Stereoselective_Synthesis_of_i_Z_i_-Fluoroalkenoates/3759741 Stereoselective syntheses of (<i>Z</i>)-fluoroalkenoates <b>3a</b>−<b>g</b> have been developed in three steps from the readily available fluorosulfide <b>5</b> and aldehydes. This preparation, involving a Durst reaction, was highly stereoselective and led to fluoroalkenes in 50−60% overall yields, without purification of intermediates. 1999-10-17 00:00:00 stereoselective Stereoselective Synthesis preparation intermediate aldehyde fluorosulfide 5 Fluoroalkenoate fluoroalkene synthese fluoroalkenoate yield purification New Route Durst reaction