Stereoselective Synthesis of
(<i>Z</i>)-2-Fluoro-1-alkenyl(phenyl)iodonium
Tetrafluoroborates
Masanori Yoshida
Shoji Hara
10.1021/ol027512y.s002
https://acs.figshare.com/articles/journal_contribution/Stereoselective_Synthesis_of_i_Z_i_-2-Fluoro-1-alkenyl_phenyl_iodonium_Tetrafluoroborates/3745560
(<i>Z</i>)-2-Fluoro-1-alkenyl(phenyl)iodonium salts were stereoselectively prepared by the reaction of alkynyl(phenyl)iodonium salts with aqueous
HF in good yields. The method is applicable to the synthesis of fluoroalkenyliodonium salts having functional groups such as ketone, ester,
and chloride. (<i>Z</i>)-2-Fluoro-1-alkene, (<i>Z</i>)-2-fluoro-2-alkenoate, and (<i>Z</i>)<i>-</i>β<i>-</i>fluoroenyne could be stereoselectively prepared from the fluoroalkenyliodonium salt.
2003-01-18 00:00:00
stereoselectively
HF
fluoroalkenyliodonium salts
Stereoselective Synthesis
fluoroalkenyliodonium salt
Fluoro