Liu, Hui Smoliakova, Irina P. Koikov, Leonid N. A One-Pot Synthesis of β-<i>C</i>-Glucopyranosides from <i>e</i><i>xo</i>-Glucal, <i>p</i>-Tolylsulfenyl Chloride, an α-Methoxyalkene, and an External Nucleophile β-<i>C</i>-Glycosides were synthesized in one-pot experiments using the following sequence of four reactions:  (i) addition of <i>p</i>-TolSCl to an α-methoxyalkene, (ii) generation of the episulfonium ion from a β-(arylsulfanyl)alkyl chloride, (iii) reaction of the episulfonium intermediate with benzylated <i>exo</i>-d-glucal to form a cyclic five-membered sulfonium salt, and (iv) quenching of the sulfonium salt with the external nucleophile:  H<sub>2</sub>O, CH<sub>3</sub>OH, or NaCNBH<sub>3</sub>. benzylated exo;CH 3 OH;sequence;generation;Glucopyranoside;sulfonium salt;NaCNBH 3;iv;ii;Glycoside;nucleophile;experiment;Glucal;External;chloride;Nucleophile;Synthesi;Tolylsulfenyl Chloride;e xo;iii;Methoxyalkene;episulfonium ion;quenching;cyclic;arylsulfanyl;methoxyalkene;TolSCl 2002-10-03
    https://acs.figshare.com/articles/journal_contribution/A_One-Pot_Synthesis_of_-_i_C_i_-Glucopyranosides_from_i_e_i_i_xo_i_-Glucal_i_p_i_-Tolylsulfenyl_Chloride_an_-Methoxyalkene_and_an_External_Nucleophile/3744210
10.1021/ol026718w.s002