10.1021/ol016200c.s001
Michael Harmata
Michael
Harmata
Paitoon Rashatasakhon
Paitoon
Rashatasakhon
A 4 + 3 Cycloaddition Approach to the
Synthesis of Spatol. A Formal Total
Synthesis of Racemic Spatol
American Chemical Society
2001
Racemic Spatol
cyclopentenyl cation
cyclopentadiene
3 cycloaddition
racemic spatol
synthesis
3 Cycloaddition Approach
Formal
rearrangement
Synthesi
2001-07-07 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/A_4_3_Cycloaddition_Approach_to_the_Synthesis_of_Spatol_A_Formal_Total_Synthesis_of_Racemic_Spatol/3739611
A formal total synthesis of racemic spatol is presented. The key steps involved a 4 + 3 cycloaddition of a halogenated cyclopentenyl cation
to cyclopentadiene and a quasi-Favorskii rearrangement.