BINOL−Salen Metal Catalysts
Incorporating a Bifunctional Design
Erin F. DiMauro
Marisa C. Kozlowski
10.1021/ol0158213.s001
https://acs.figshare.com/articles/journal_contribution/BINOL_Salen_Metal_Catalysts_Incorporating_a_Bifunctional_Design/3739035
Salen metal complexes incorporating two chiral BINOL moieties have been synthesized and characterized crystallographically. The corresponding
bisnaphthoxide complexes have been found to catalyze the asymmetric addition of benzyl malonate to cyclohexenone in up to 90% ee. With
these modular catalysts, the Lewis acid and Bronsted base portions can be independently altered.
2001-05-03 00:00:00
ee
catalyze
bisnaphthoxide complexes
Catalyst
Bronsted base portions
benzyl malonate
Lewis acid
cyclohexenone
crystallographically
catalyst
Bifunctional Design Salen metal complexes
chiral BINOL moieties
Incorporating