BINOL−Salen Metal Catalysts Incorporating a Bifunctional Design Erin F. DiMauro Marisa C. Kozlowski 10.1021/ol0158213.s001 https://acs.figshare.com/articles/journal_contribution/BINOL_Salen_Metal_Catalysts_Incorporating_a_Bifunctional_Design/3739035 Salen metal complexes incorporating two chiral BINOL moieties have been synthesized and characterized crystallographically. The corresponding bisnaphthoxide complexes have been found to catalyze the asymmetric addition of benzyl malonate to cyclohexenone in up to 90% ee. With these modular catalysts, the Lewis acid and Bronsted base portions can be independently altered. 2001-05-03 00:00:00 ee catalyze bisnaphthoxide complexes Catalyst Bronsted base portions benzyl malonate Lewis acid cyclohexenone crystallographically catalyst Bifunctional Design Salen metal complexes chiral BINOL moieties Incorporating