%0 Journal Article
%A Malkov, Andrei V.
%A Bella, Marco
%A Langer, Vratislav
%A Kočovský, Pavel
%D 2000
%T PINDY: A Novel, Pinene-Derived
Bipyridine Ligand and Its Application in
Asymmetric, Copper(I)-Catalyzed Allylic
Oxidation†
%U https://acs.figshare.com/articles/journal_contribution/PINDY_A_Novel_Pinene-Derived_Bipyridine_Ligand_and_Its_Application_in_Asymmetric_Copper_I_-Catalyzed_Allylic_Oxidation_sup_sup_/3736647
%R 10.1021/ol006111k.s001
%2 https://acs.figshare.com/ndownloader/files/5828415
%K bipyridine
%K Ligand
%K ee
%K Allylic
%K Application
%K catalyze
%K Triflate 9
%K crystallography
%K CuCl 2
%K rt
%K Asymmetric
%K pinene
%K allylic oxidation
%K PINDY
%K ligand
%K Bipyridine
%K min
%K Oxidation
%X The title bipyridine ligand (+)-6(PINDY), prepared in five steps from (−)-β-pinene, forms a stable complex with CuCl2 (8) that has been characterized
by X-ray crystallography to reveal an unusual geometry at Cu. Triflate 9 proved to catalyze asymmetric allylic oxidation (10 → 11; rt, ∼30 min,
49−75% ee).
%I ACS Publications