2,6-Dichloro-9-thiabicyclo[3.3.1]nonane:  A Privileged, Bivalent Scaffold for the Display of Nucleophilic Components Antonella Converso Kristina Burow Andreas Marzinzik K. Barry Sharpless M. G. Finn 10.1021/jo015632y.s002 https://acs.figshare.com/articles/journal_contribution/2_6-Dichloro-9-thiabicyclo_3_3_1_nonane_A_Privileged_Bivalent_Scaffold_for_the_Display_of_Nucleophilic_Components/3691398 The title compound, the condensation product of sulfur dichloride and 1,5-cyclooctadiene, is a reliable acceptor of a wide variety of heteroatom nucleophiles, sometimes in reversible fashion. Optical resolution of the core structure has been achieved and preserved in succeeding transformations. The high reactivity and reliable stereochemical control afforded by this system illustrates the power of neighboring-group participation by the sulfur center. 2001-05-23 00:00:00 fashion sulfur center sulfur dichloride condensation product Privileged cyclooctadiene reactivity core structure Bivalent Scaffold transformation participation title compound stereochemical control heteroatom nucleophiles Display acceptor Dichloro Nucleophilic Components Optical resolution variety