%0 Journal Article
%A Murahashi, Tetsuro
%A Higuchi, Yutaka
%A Katoh, Tetsuya
%A Kurosawa, Hideo
%D 2002
%T Photoinduced Face-Inversion of Conjugated Tetraene Ligands on a
Pd−Pd−Pd Moiety
%U https://acs.figshare.com/articles/journal_contribution/Photoinduced_Face-Inversion_of_Conjugated_Tetraene_Ligands_on_a_Pd_Pd_Pd_Moiety/3641481
%R 10.1021/ja0208254.s001
%2 https://acs.figshare.com/ndownloader/files/5730288
%K tetraene ligands
%K photoinduced isomerization
%K BAr f
%K rac
%K Conjugated Tetraene Ligands
%K meso isomers
%K Pd 3
%K sandwich tripalladium complexes
%X The linear sandwich tripalladium complexes [Pd3{Ar(CHCH)4Ar}2[BArf]2 (Ar = Ph, p-t-Bu-C6H4, p-styryl-C6H4) undergo photoinduced isomerization involving face-inversion of the tetraene ligands. Irradiation of these complexes with visible light (>510 nm) resulted in rac (staggered sandwich) to meso (eclipsed sandwich) isomerization. The structures of rac and meso isomers are determined by X-ray crystallographic analyses.
%I ACS Publications