Aqueous High-Temperature Chemistry of Carbo- and Heterocycles. 28. Reactions of Aryl Sulfoxides and Sulfones in Sub- and Supercritical Water at 200−460 °C Alan R. Katritzky Richard A. Barcock Elena S. Ignatchenko Steven M. Allin Michael Siskin Carl W. Hudson 10.1021/ef960073x.s001 https://acs.figshare.com/articles/journal_contribution/Aqueous_High-Temperature_Chemistry_of_Carbo-_and_Heterocycles_28_Reactions_of_Aryl_Sulfoxides_and_Sulfones_in_Sub-_and_Supercritical_Water_at_200_460_C/3595971 Diphenyl and methyl phenyl sulfones and sulfoxides and dibenzothiophene sulfone were treated at 460 °C with water, 15% aqueous formic acid, and 15% aqueous sodium formate. Thermal comparisons were run in cyclohexane, and for those compounds and conditions that resulted in fast conversion after 7 min at 460 °C, also at lower temperatures. Sulfoxides are highly reactive, sulfones less so. Reactivity is greatest in 15% aqueous sodium formate followed by formic acid for the sulfones; this reactivity order is inverted for the sulfoxides. In all of the aqueous media, ionic reactions dominate. The sulfoxides are mainly deoxygenated to the corresponding sulfides, while C−S bond cleavage is more important for the sulfones. Product slates are identified and analyzed, and reaction pathways are suggested for the transformations found. 1997-01-21 00:00:00 formic acid Sulfoxide sulfoxide methyl phenyl sulfones sodium formate