Chang, Jian Liu, Bangyu Yang, Yang Wang, Mang Pd-Catalyzed C–S Activation/Isocyanide Insertion/Hydrogenation Enables a Selective Aerobic Oxidation/Cyclization Unique imidoylation of thioorganics with isocyanides endows an unprecedented aerobic oxidation process. Catalyzed by Pd­(Ph<sub>3</sub>P)<sub>2</sub>Cl<sub>2</sub> in the presence of Ph<sub>3</sub>SiH under N<sub>2</sub> then upon exposure to air, a wide range of α-acyl ketene dithioacetals react with isocyanides to afford 5-hydroxy-α,β-unsaturated γ-lactams via a C–S bond activation, isocyanide migratory insertion, hydrogenation, selective aerobic oxidation, and intramolecular nucleophilic addition sequence. 2 Cl 2;oxidation process;Ph 3 SiH;isocyanide;intramolecular nucleophilic addition sequence;N 2 2016-08-07
    https://acs.figshare.com/articles/dataset/Pd-Catalyzed_C_S_Activation_Isocyanide_Insertion_Hydrogenation_Enables_a_Selective_Aerobic_Oxidation_Cyclization/3545423
10.1021/acs.orglett.6b01780.s002