%0 Journal Article
%A Chen, Teng-Hao
%A Wang, Le
%A Trueblood, Jonathan
V.
%A Grassian, Vicki H.
%A Cohen, Seth M.
%D 2016
%T Poly(isophthalic
acid)(ethylene oxide) as a Macromolecular
Modulator for Metal–Organic Polyhedra
%U https://acs.figshare.com/articles/journal_contribution/Poly_isophthalic_acid_ethylene_oxide_as_a_Macromolecular_Modulator_for_Metal_Organic_Polyhedra/3496235
%R 10.1021/jacs.6b04971.s001
%2 https://acs.figshare.com/ndownloader/files/5525225
%K reaction conditions
%K MOP crystals
%K MOP particles
%K glass surfaces
%K modulator strategy
%K MOP structures
%K polymer ligand
%K isophthalic acid derivatives
%K Cu 24 L 24
%K Macromolecular Modulator
%K oxide
%K crystal habit
%X A new
strategy was developed by using a polymer ligand, poly(isophthalic
acid)(ethylene oxide), to modulate the growth of metal–organic
polyhedra (MOP) crystals. This macromolecular modulator can effectively
control the crystal habit of several different Cu24L24 (L = isophthalic acid derivatives) MOPs. The polymer also
directed the formation of MOP structures under reaction conditions
that only produce metal–organic frameworks in the absence of
modulator. Moreover, the polymer also enabled the deposition of MOP
crystals on glass surfaces. This macromolecular modulator strategy
provides an innovative approach to control the morphology and assembly
of MOP particles.
%I ACS Publications