%0 Generic
%A Amoore, Jarrod J. M.
%A Black, Cory A.
%A Hanton, Lyall R.
%A Spicer, Mark D.
%D 2005
%T Increasing Structural Dimensionality in Ag(I)
Coordination Polymers Formed from the Same Flexible
Multimodal Thioether Pyrazine Ligand
%U https://acs.figshare.com/articles/dataset/Increasing_Structural_Dimensionality_in_Ag_I_Coordination_Polymers_Formed_from_the_Same_Flexible_Multimodal_Thioether_Pyrazine_Ligand/3373918
%R 10.1021/cg050011+.s001
%2 https://acs.figshare.com/ndownloader/files/5217394
%K BF
%K dimensionality
%K L ratio
%K benzene
%K PF
%K Multimodal Thioether Pyrazine Ligand
%K AgPF
%K CH 2 Cl 2
%K coordination polymers
%K 4.8 2 nets
%K Coordination arrays 2
%K mix
%X Three coordination polymers were prepared by the reaction of a new flexible multimodal ligand, bis(2-pyrazylmethyl)sulfide (L), with AgX salts (X = BF4- or PF6-). The polymers showed an increasing dimensionality
from 1-D to 2-D to 3-D, and the influence of solvent and anion on the formation and dimensionality of these
coordination polymers was explored. A 1-D twisted ladder-like polymer with η-bound benzene and a 2:1 AgPF6-to-L ratio, 1·MeCN, was formed when benzene was present in the solvent mix. A 2-D undulating sheet with 4.8
topology and a 1:1 AgPF6-to-L ratio, 2, was formed when CH2Cl2 was present in the solvent mix. A 3-D network, 3,
with two different 4.82 nets linked together by 4.85 bridging nodes was formed when a 1:1 AgBF4-to-L ratio was
used and MeNO2 was present in the solvent mix. Coordination arrays 2 and 3 were found to be related topologically.
%I ACS Publications