%0 Journal Article
%A R. St.-J. Foreman, Mark
%A Hill, Anthony F.
%A White, P.
%A Williams, David J.
%D 2004
%T Polyazolyl Chelate Chemistry. 13. An Osmaboratrane1
%U https://acs.figshare.com/articles/journal_contribution/Polyazolyl_Chelate_Chemistry_13_An_Osmaboratrane_sup_1_sup_/3349930
%R 10.1021/om0306123.s001
%2 https://acs.figshare.com/ndownloader/files/5189242
%K crystal structure
%K Na
%K benzene elimination
%K boron
%K 13.
%K methimazolyl
%K osmium
%K Osmaboratrane 1
%K Polyazolyl Chelate Chemistry
%K formation
%K Cl
%K transannular dative bond
%K mt
%K osmaboratrane
%X The reaction of [Os(C6H5)Cl(CO)(PPh3)2] with
Na[HB(mt)3] (mt = methimazolyl) results in benzene
elimination and the formation of the first osmaboratrane
[B(mt)3Os(CO)(PPh3)](Os→B), the crystal structure of
which reveals a somewhat long transannular dative
bond between osmium(0) and boron(III).
%I ACS Publications