Andrukiewicz, Robert Cmoch, Piotr Gaweł, Anna Staliński, Krzysztof Stereoselection at the Steady State in Radical Cyclizations of Acyclic Systems Containing One Radical Acceptor and Two Precursors in a 1,5- Relationship under Pseudo-First-Order Conditions<sup>†</sup> The first example of a successive kinetic resolution of acyclic diastereomeric radical intermediates in a 1,5-relationship under pseudo-first-order conditions is reported. A mechanistic model involves nonselective generation of the radical intermediates followed by different partitioning of these between two different chemical pathways. The “2,5-<i>cis</i>” selectivity in the radical cyclization step arises from transition geometries with the substituents aligned in pseudoequatorial positions. Radical Cyclizations;selectivity;chemical pathways;transition geometries;cyclization step;Relationship;ci;Acyclic Systems Containing;intermediate;nonselective generation;relationship;Precursor;substituent;pseudoequatorial positions;Steady State;acyclic diastereomeric;model;Radical Acceptor;partitioning;Stereoselection 2004-03-19
    https://acs.figshare.com/articles/journal_contribution/Stereoselection_at_the_Steady_State_in_Radical_Cyclizations_of_Acyclic_Systems_Containing_One_Radical_Acceptor_and_Two_Precursors_in_a_1_5_Relationship_under_Pseudo_First_Order_Conditions_sup_sup_/3345838
10.1021/jo035310p.s001