Formation of Inclusion Organoactinide Complexes with Boron-Containing
Macrocycles
Eyal Barnea
Tamer Andrea
Moshe Kapon
Moris S. Eisen
10.1021/ja0498843.s005
https://acs.figshare.com/articles/dataset/Formation_of_Inclusion_Organoactinide_Complexes_with_Boron_Containing_Macrocycles/3341677
Reaction of the organoactinide complexes (C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>AnMe<sub>2</sub> (An = Th, U) with catecholborane yields an inclusion complex where the actinide is encapsulated inside a 15-membered, hexaoxo, trianionic macrocycle built from alternating catechol and catecholborate fragments. In the presence of LiOH, a dimer of two encapsulated actinide macrocycles is formed. The X-ray molecular structure for all the complexes is presented.
2004-04-28 00:00:00
inclusion
Inclusion Organoactinide Complexes
C 5
LiOH
Th
presence
organoactinide complexes
hexaoxo
encapsulated actinide macrocycles
2 AnMe 2
formation
membered
Macrocycle
catecholborate fragments
trianionic macrocycle
catecholborane yields
dimer