10.1021/om049449h.s005
Myeongsoon Kang
Myeongsoon
Kang
Ayusman Sen
Ayusman
Sen
Reaction of Palladium 1,5-Cyclooctadiene Alkyl Chloride
with Norbornene Derivatives: Relevance to
Metal-Catalyzed Addition Polymerization of
Functionalized Norbornenes
American Chemical Society
2004
carboxylic
bicyclo
insertion
acid
ethyl
ester
endo
Functionalized Norbornenes
exo face
2004-11-08 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Reaction_of_Palladium_1_5_Cyclooctadiene_Alkyl_Chloride_with_Norbornene_Derivatives_Relevance_to_Metal_Catalyzed_Addition_Polymerization_of_Functionalized_Norbornenes/3317089
The insertions of norbornene, bicyclo[2.2.1]hept-5-ene-<i>endo</i>-2-carboxylic acid ethyl ester, bicyclo[2.2.1]hept-5-ene-<i>exo</i>-2-carboxylic acid ethyl ester, and
bicyclo[2.2.1]hept-5-enyl-<i>endo</i>-2-methyl acetate into the
palladium−methyl bond of (η<sup>4</sup>-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar
rates, with the product in every case being derived from
insertion through the exo face.