Structural and Spectroscopic Characterization of (μ-Hydroxo or
μ-Oxo)(μ-peroxo)diiron(III) Complexes: Models for Peroxo Intermediates of
Non-Heme Diiron Proteins
Xi Zhang
Hideki Furutachi
Shuhei Fujinami
Shigenori Nagatomo
Yonezo Maeda
Yoshihito Watanabe
Teizo Kitagawa
Masatatsu Suzuki
10.1021/ja045594a.s002
https://acs.figshare.com/articles/journal_contribution/Structural_and_Spectroscopic_Characterization_of_Hydroxo_or_Oxo_peroxo_diiron_III_Complexes_Models_for_Peroxo_Intermediates_of_Non_Heme_Diiron_Proteins/3303343
(μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe<sub>2</sub>(μ-OH or μ-O)(μ-O<sub>2</sub>)(L)<sub>2</sub>]<i><sup>n</sup></i><sup>+</sup> were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.
2005-01-26 00:00:00
model
peroxodiiron
Diiron
spectroscopic insights
Fe
analysis
Peroxo Intermediates
protein
diiron
tetradentate tripodal ligand
carboxylate sidearm
complex
Spectroscopic Characterization
physicochemical measurements
Structural
Hydroxo
Proteins
Complexe
Oxo
Model
OH