Structural and Spectroscopic Characterization of (μ-Hydroxo or μ-Oxo)(μ-peroxo)diiron(III) Complexes:  Models for Peroxo Intermediates of Non-Heme Diiron Proteins Xi Zhang Hideki Furutachi Shuhei Fujinami Shigenori Nagatomo Yonezo Maeda Yoshihito Watanabe Teizo Kitagawa Masatatsu Suzuki 10.1021/ja045594a.s002 https://acs.figshare.com/articles/journal_contribution/Structural_and_Spectroscopic_Characterization_of_Hydroxo_or_Oxo_peroxo_diiron_III_Complexes_Models_for_Peroxo_Intermediates_of_Non_Heme_Diiron_Proteins/3303343 (μ-Hydroxo or oxo)(μ-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe<sub>2</sub>(μ-OH or μ-O)(μ-O<sub>2</sub>)(L)<sub>2</sub>]<i><sup>n</sup></i><sup>+</sup> were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes. 2005-01-26 00:00:00 model peroxodiiron Diiron spectroscopic insights Fe analysis Peroxo Intermediates protein diiron tetradentate tripodal ligand carboxylate sidearm complex Spectroscopic Characterization physicochemical measurements Structural Hydroxo Proteins Complexe Oxo Model OH