%0 Journal Article
%A Li, Hong-Xi
%A Ren, Zhi-Gang
%A Zhang, Yong
%A Zhang, Wen-Hua
%A Lang, Jian-Ping
%A Shen, Qi
%D 2005
%T Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from
Preformed Complexes [(TMS)2N]3Ln(μ-Cl)Li(THF)3 (Ln = Pr, Nd, Sm; (TMS)2N
= Bis(trimethylsilyl)amide)
%U https://acs.figshare.com/articles/journal_contribution/Construction_of_Polymeric_and_Oligomeric_Lanthanide_III_Thiolates_from_Preformed_Complexes_TMS_sub_2_sub_N_sub_3_sub_Ln_Cl_Li_THF_sub_3_sub_Ln_Pr_Nd_Sm_TMS_sub_2_sub_N_Bis_trimethylsilyl_amide_/3302608
%R 10.1021/ja043415j.s006
%2 https://acs.figshare.com/ndownloader/files/5140342
%K Ln
%K SPh
%K TMS
%K square Sm 4 array
%K μ 3
%K ligand
%K Cl
%K 2 N
%X The complex [{(TMS)2N}4(μ4-Cl)Sm4(μ-SPh)4(μ3-Cl)Li(THF)] has been formed by protonolysis of [(Me3Si)2N]3Sm(μ-Cl)Li(THF)3 with 1 equiv of HSPh, which contains a square array of Sm(III) ions connected by a central μ4-Cl ligand. The edges of the square Sm4 array are bridged by four μ3-Cl and four μ-SPh ligands. The four Sm atoms and Li atom are connected by four μ3-Cl ligands.
%I ACS Publications