%0 Journal Article %A Li, Hong-Xi %A Ren, Zhi-Gang %A Zhang, Yong %A Zhang, Wen-Hua %A Lang, Jian-Ping %A Shen, Qi %D 2005 %T Construction of Polymeric and Oligomeric Lanthanide(III) Thiolates from Preformed Complexes [(TMS)2N]3Ln(μ-Cl)Li(THF)3 (Ln = Pr, Nd, Sm; (TMS)2N = Bis(trimethylsilyl)amide) %U https://acs.figshare.com/articles/journal_contribution/Construction_of_Polymeric_and_Oligomeric_Lanthanide_III_Thiolates_from_Preformed_Complexes_TMS_sub_2_sub_N_sub_3_sub_Ln_Cl_Li_THF_sub_3_sub_Ln_Pr_Nd_Sm_TMS_sub_2_sub_N_Bis_trimethylsilyl_amide_/3302608 %R 10.1021/ja043415j.s006 %2 https://acs.figshare.com/ndownloader/files/5140342 %K Ln %K SPh %K TMS %K square Sm 4 array %K μ 3 %K ligand %K Cl %K 2 N %X The complex [{(TMS)2N}44-Cl)Sm4(μ-SPh)43-Cl)Li(THF)] has been formed by protonolysis of [(Me3Si)2N]3Sm(μ-Cl)Li(THF)3 with 1 equiv of HSPh, which contains a square array of Sm(III) ions connected by a central μ4-Cl ligand. The edges of the square Sm4 array are bridged by four μ3-Cl and four μ-SPh ligands. The four Sm atoms and Li atom are connected by four μ3-Cl ligands. %I ACS Publications