10.1021/ic048648q.s002 Bao-Qing Ma Bao-Qing Ma Hao-Ling Sun Hao-Ling Sun Song Gao Song Gao Assembly of Hydrogen Bonded Diamondoid Networks Based on Synthetic Metal-Organic Tetrahedral Nodes American Chemical Society 2005 Synthetic hydrogen bonds species tetrahedral moieties metal centers water molecules H 2 O assembly Hydrogen Bonded Diamondoid Networks Mn octahedral environment tetrahedral configuration Co 3 D diamondoid networks dpdo ligands Tetrahedral 2005-02-21 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Assembly_of_Hydrogen_Bonded_Diamondoid_Networks_Based_on_Synthetic_Metal_Organic_Tetrahedral_Nodes/3300109 Reaction of Mn(ClO<sub>4</sub>)<sub>2</sub> or Co(PF<sub>6</sub>)<sub>2</sub> with 4,4‘-dipyridine-dioxide (dpdo) produced novel molecular species [M(dpdo)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup>, which hold a tetrahedral configuration notwithstanding their octahedral environment around the metal centers. The tetrahedral moieties are further assembled through hydrogen bonds between peripheral NO ends of dpdo ligands and coordinated water molecules, giving rise to 3D diamondoid networks.