10.1021/ic048648q.s002
Bao-Qing Ma
Bao-Qing
Ma
Hao-Ling Sun
Hao-Ling
Sun
Song Gao
Song
Gao
Assembly of Hydrogen Bonded Diamondoid Networks Based on
Synthetic Metal-Organic Tetrahedral Nodes
American Chemical Society
2005
Synthetic
hydrogen bonds
species
tetrahedral moieties
metal centers
water molecules
H 2 O
assembly
Hydrogen Bonded Diamondoid Networks
Mn
octahedral environment
tetrahedral configuration
Co
3 D diamondoid networks
dpdo ligands
Tetrahedral
2005-02-21 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Assembly_of_Hydrogen_Bonded_Diamondoid_Networks_Based_on_Synthetic_Metal_Organic_Tetrahedral_Nodes/3300109
Reaction of Mn(ClO<sub>4</sub>)<sub>2</sub> or Co(PF<sub>6</sub>)<sub>2</sub> with 4,4‘-dipyridine-dioxide
(dpdo) produced novel molecular species [M(dpdo)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>]<sup>2+</sup>, which
hold a tetrahedral configuration notwithstanding their octahedral
environment around the metal centers. The tetrahedral moieties
are further assembled through hydrogen bonds between peripheral
NO ends of dpdo ligands and coordinated water molecules, giving
rise to 3D diamondoid networks.