An Infinite Water Chain Passes through an Array of Zn(II) Metallocycles
Built with a Podand Bearing Terminal Carboxylates
Subhadip Neogi
Parimal K. Bharadwaj
10.1021/ic048489a.s002
https://acs.figshare.com/articles/dataset/An_Infinite_Water_Chain_Passes_through_an_Array_of_Zn_II_Metallocycles_Built_with_a_Podand_Bearing_Terminal_Carboxylates/3300058
A podand bearing three carboxylic acid groups was synthesized
by condensation of tris(2-chloroethyl)amine with 4-hydroxyethylbenzoate followed by hydrolysis of the ester group. An aqueous
solution of Zn(NO<sub>3</sub>)<sub>2</sub>ยท6H<sub>2</sub>O reacts with the tetraethylammonium salt
of the podand at room temperature, to form a porous coordination
polymeric structure with infinite interlinked chains of Zn(II) metallocycles. An infinite water chain passes through the metallocycles
like a thread. The compound was characterized by X-ray
crystallography, X-ray powder diffraction, TGA, IR spectroscopy,
and elemental analysis.
2005-02-21 00:00:00
tetraethylammonium salt
podand
ester group
IR spectroscopy
water chain
carboxylic acid groups
Infinite Water Chain Passes
Podand Bearing Terminal Carboxylates
TGA
Zn
metallocycle
room temperature