10.1021/ic0484957.s001 Ding-xian Jia Ding-xian Jia Qin-Yu Zhu Qin-Yu Zhu Jie Dai Jie Dai Wen Lu Wen Lu Wen-Juan Guo Wen-Juan Guo The First Example of Solvothermally Synthesized Thioantimonates(V) with Ethylenediamine Coordinated Lanthanide(III):  [Sm(en)<sub>4</sub>]SbS<sub>4</sub>·0.5en and [Sm(en)<sub>3</sub>(H<sub>2</sub>O)(<i>μ</i>-SbS<sub>4</sub>)]<sub>∞</sub> American Chemical Society 2005 H 2 O SbS 4 solvothermal conditions First Example Sm 2005-02-21 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/The_First_Example_of_Solvothermally_Synthesized_Thioantimonates_V_with_Ethylenediamine_Coordinated_Lanthanide_III_Sm_en_sub_4_sub_SbS_sub_4_sub_0_5en_and_Sm_en_sub_3_sub_H_sub_2_sub_O_i_i_SbS_sub_4_sub_sub_sub_/3300052 Under mild solvothermal conditions two novel thioantimonates(V) [Sm(en)<sub>4</sub>]SbS<sub>4</sub>·0.5en (<b>1</b>) and [Sm(en)<sub>3</sub>(H<sub>2</sub>O)(μ-SbS<sub>4</sub>)]<sub>∞</sub> (<b>2</b>) were synthesized; the structure of <b>1</b> contains discrete [Sm(en)<sub>4</sub>]<sup>3+</sup> and [SbS<sub>4</sub>]<sup>3-</sup> ions, while <b>2</b> consists of neutral [Sm(en)<sub>3</sub>(H<sub>2</sub>O) (μ-SbS<sub>4</sub>)] one-dimensional chains.