%0 Journal Article %A Sentman, Alan C. %A Csihony, Szilárd %A Waymouth, Robert M. %A Hedrick, James L. %D 2005 %T Silver(I)−Carbene Complexes/Ionic Liquids:  Novel N-Heterocyclic Carbene Delivery Agents for Organocatalytic Transformations %U https://acs.figshare.com/articles/journal_contribution/Silver_I_Carbene_Complexes_Ionic_Liquids_Novel_i_N_i_Heterocyclic_Carbene_Delivery_Agents_for_Organocatalytic_Transformations/3295831 %R 10.1021/jo048555q.s001 %2 https://acs.figshare.com/ndownloader/files/5133568 %K Organocatalytic Transformations N %K silver complexes %K zwitterionic CS 2 adducts %K NHC carbene catalysts %K Heterocyclic Carbene Delivery Agents %K Heterocyclic carbene %K CS 2 %K molecule transesterification reactions %X N-Heterocyclic carbene (NHC) complexes with silver were investigated as sources of unsaturated NHC carbene catalysts via thermal decomposition. The NHC complex (1-ethyl-3-methylimidazol-2-ylidene)silver(I) chloride is an ionic liquid, and was found to catalyze the ring-opening polymerization of lactide at elevated temperatures to give narrowly dispersed polylactide of predictable molecular weight. Silver−carbene complexes can also be used for the catalysis of small molecule transesterification reactions. Thermolysis of the silver complexes in the presence of CS2 yielded the zwitterionic CS2 adducts of the carbene, implicating the intermediacy of the free carbene in these reactions. %I ACS Publications