Yeung, Siu Kwan Chan, Kin Shing 1,2-Rearrangements of β-Nitrogen-Substituted (Porphyrinato)rhodium(III) Ethyls (Porphyrinato)rhodium(III) ethyls containing β-nitrogen substituents have been showed to undergo clean, thermal 1,2-rearrangements into the α-nitrogen-substituted rhodium ethyls. The rates and the equilibrium positions were found to be dependent on the electronic nature of the N substituents. Complexes <b>1a</b>−<b>3a</b> were characterized by X-ray crystallography. Porphyrinato;crystallography;ethyl;Complexes 1;equilibrium positions;rhodium;N substituents;nature;Rearrangement;rearrangement;Ethyl 2005-05-23
    https://acs.figshare.com/articles/dataset/1_2_Rearrangements_of_Nitrogen_Substituted_Porphyrinato_rhodium_III_Ethyls/3285343
10.1021/om0501475.s006