Recyclable Self-Assembly-Supported
Catalytic System for Orthoalkylation
Jong Huem Yoon
Young Jun Park
Jun Hee Lee
Jaeho Yoo
Chul-Ho Jun
10.1021/ol050865n.s001
https://acs.figshare.com/articles/journal_contribution/Recyclable_Self_Assembly_Supported_Catalytic_System_for_Orthoalkylation/3278524
A new recyclable supported catalyst system for orthoalkylation was devised using a self-assembly consisting of the barbiturate and 2,4,6-triaminopyrimidine H-bonding motifs. At high temperature, the system is completely homogeneous so as to give an efficient catalytic activity,
while it is heterogenized at room temperature to form an insoluble solid phase for the easy recovery of the catalyst after the reaction.
2005-07-07 00:00:00
motif
Catalytic
barbiturate
heterogenized
Orthoalkylation
phase
recovery
triaminopyrimidine
orthoalkylation
Recyclable
room temperature
catalyst system