%0 Journal Article
%A Miyasaka, Hitoshi
%A Takahashi, Hitomi
%A Madanbashi, Tomokura
%A Sugiura, Ken-ichi
%A Clérac, Rodolphe
%A Nojiri, Hiroyuki
%D 2005
%T Cyano-Bridged MnIII3MIII (MIII = Fe, Cr) Complexes: Synthesis, Structure,
and Magnetic Properties
%U https://acs.figshare.com/articles/journal_contribution/Cyano_Bridged_Mn_sup_III_sup_sub_3_sub_M_sup_III_sup_M_sup_III_sup_Fe_Cr_Complexes_Synthesis_Structure_and_Magnetic_Properties/3271810
%R 10.1021/ic0505753.s001
%2 https://acs.figshare.com/ndownloader/files/5109529
%K salen
%K CN
%K Fe
%K NH
%K Mn
%K tridentate building block
%K M III
%K dependence
%K C 12 H 25
%K Cr
%X Two cyano-bridged tetranuclear complexes composed of Mn(III)
salen (salen = N,N‘-ethylene bis(salicylideneiminate)) and hexacyanometalate(III) (M = Fe, Cr) in a stoichiometry of 3:1 have been
selectively synthesized using {NH2(n-C12H25)2}3[MIII(CN)6] (MIII =
Fe, Cr) starting materials: [{Mn(salen)(EtOH)}3{M(CN)6}] (M =
Fe, 1; Cr, 2). Compounds 1 and 2 are isostructural with a T-shaped
structure, in which [M(CN)6]3- assumes a meridional-tridentate
building block to bind three [Mn(salen)(EtOH)]+ units. The strong
frequency dependence and observation of hysteresis on the field
dependence of the magnetization indicate that 1 is a single-molecule magnet.
%I ACS Publications