Synthesis and Chemistry of Bridgehead
Allylsilanes. Stereoselective Reactions
with Aldehydes
Ryan Lauchli
John M. Whitney
Liang Zhu
Kenneth J. Shea
10.1021/ol051363c.s001
https://acs.figshare.com/articles/journal_contribution/Synthesis_and_Chemistry_of_Bridgehead_Allylsilanes_Stereoselective_Reactions_with_Aldehydes/3270385
A type II intramolecular DielsāAlder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The
Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.
2005-09-01 00:00:00
Lewis acid
bicyclo
intramolecular
Aldehyde
type
bridgehead allylsilane
access
Stereoselective Reactions
Diel
Bridgehead Allylsilanes
stereochemistry
Synthesi
aldehyde
II
compound