Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes Ryan Lauchli John M. Whitney Liang Zhu Kenneth J. Shea 10.1021/ol051363c.s001 https://acs.figshare.com/articles/journal_contribution/Synthesis_and_Chemistry_of_Bridgehead_Allylsilanes_Stereoselective_Reactions_with_Aldehydes/3270385 A type II intramolecular Dielsāˆ’Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry. 2005-09-01 00:00:00 Lewis acid bicyclo intramolecular Aldehyde type bridgehead allylsilane access Stereoselective Reactions Diel Bridgehead Allylsilanes stereochemistry Synthesi aldehyde II compound