10.1021/ol051363c.s001 Ryan Lauchli Ryan Lauchli John M. Whitney John M. Whitney Liang Zhu Liang Zhu Kenneth J. Shea Kenneth J. Shea Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes American Chemical Society 2005 Lewis acid bicyclo intramolecular Aldehyde type bridgehead allylsilane access Stereoselective Reactions Diel Bridgehead Allylsilanes stereochemistry Synthesi aldehyde II compound 2005-09-01 00:00:00 Journal contribution https://acs.figshare.com/articles/journal_contribution/Synthesis_and_Chemistry_of_Bridgehead_Allylsilanes_Stereoselective_Reactions_with_Aldehydes/3270385 A type II intramolecular Dielsāˆ’Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.