10.1021/ol051363c.s001
Ryan Lauchli
Ryan
Lauchli
John M. Whitney
John M.
Whitney
Liang Zhu
Liang
Zhu
Kenneth J. Shea
Kenneth J.
Shea
Synthesis and Chemistry of Bridgehead
Allylsilanes. Stereoselective Reactions
with Aldehydes
American Chemical Society
2005
Lewis acid
bicyclo
intramolecular
Aldehyde
type
bridgehead allylsilane
access
Stereoselective Reactions
Diel
Bridgehead Allylsilanes
stereochemistry
Synthesi
aldehyde
II
compound
2005-09-01 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Synthesis_and_Chemistry_of_Bridgehead_Allylsilanes_Stereoselective_Reactions_with_Aldehydes/3270385
A type II intramolecular DielsāAlder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The
Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry.