10.1021/om050619f.s001
David S. Laitar
David S.
Laitar
Peter Müller
Peter
Müller
Thomas G. Gray
Thomas G.
Gray
Joseph P. Sadighi
Joseph P.
Sadighi
A Carbene-Stabilized Gold(I) Fluoride: Synthesis and
Theory
American Chemical Society
2005
DFT calculations show
fluorine
NHC
Fluoride
monomeric
charge
isolable
Synthesi
carbene
ligand
interaction
fluoride
2005-09-12 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/A_Carbene_Stabilized_Gold_I_Fluoride_Synthesis_and_Theory/3268804
The first isolable gold(I) fluoride complex,
stabilized by an N-heterocyclic carbene (NHC) ligand,
has been isolated in two-coordinate monomeric form.
DFT calculations show significant pπ/dπ interactions
between fluoride and gold(I) and indicate a substantial
negative charge on fluorine.