Highly Stereoselective [2,3]-Sigmatropic Rearrangement of Sulfur Ylide
Generated through Cu(I) Carbene and Sulfides
Ming Ma
Lingling Peng
Changkun Li
Xiu Zhang
Jianbo Wang
10.1021/ja055021d.s002
https://acs.figshare.com/articles/dataset/Highly_Stereoselective_2_3_Sigmatropic_Rearrangement_of_Sulfur_Ylide_Generated_through_Cu_I_Carbene_and_Sulfides/3259582
A highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and allyl and propargyl sulfides by a double asymmetric induction approach that combines a chiral camphor sultam auxiliary and Cu(I) catalyst with chiral or achiral diimine ligands has been developed.
2005-11-02 00:00:00
sulfur ylide
propargyl sulfides
achiral diimine ligands
chiral camphor sultam
Sulfur Ylide Generated
induction approach
Cu