Lim, Yeon-Hee Li, Tindy Chen, Peiling Schreiber, Patrick Kuznetsova, Larissa Carroll, Patrick J. Lauher, Joseph W. Sieburth, Scott McN. Asymmetry by Electrophilic Rearrangement of Symmetric 2-Pyridone Photodimers Halogenation of achiral <i>trans</i>-2-pyridone photodimers results in 1,3-migration of an amide nitrogen and formation of a chiral structure with six stereogenic centers and well-differentiated functionality. The reactivity of this product toward nucleophiles, including the allylic halide, is dominated by participation by the amide nitrogen. photodimer;Electrophilic;Symmetric;stereogenic;allylic;reactivity;Halogenation;Asymmetry;halide;functionality;amide nitrogen;participation;Pyridone;achiral;formation;Rearrangement;nucleophile;center;pyridone;chiral;tran;Photodimer;migration 2005-11-24
    https://acs.figshare.com/articles/dataset/Asymmetry_by_Electrophilic_Rearrangement_of_Symmetric_2_Pyridone_Photodimers/3255484
10.1021/ol052071e.s003