%0 Generic %A Zhan, Miao %A Li, Ren-Zhe %A Mou, Ze-Dong %A Cao, Chao-Guo %A Liu, Jie %A Chen, Yuan-Wei %A Niu, Dawen %D 2016 %T Silver-Assisted, Iridium-Catalyzed Allylation of Bis[(pinacolato)boryl]methane Allows the Synthesis of Enantioenriched Homoallylic Organoboronic Esters %U https://acs.figshare.com/articles/dataset/Silver_Assisted_Iridium_Catalyzed_Allylation_of_Bis_pinacolato_boryl_methane_Allows_the_Synthesis_of_Enantioenriched_Homoallylic_Organoboronic_Esters/3201388 %R 10.1021/acscatal.6b00719.s002 %2 https://acs.figshare.com/ndownloader/files/5025421 %K presence %K homoallylic organoboronic esters %K Enantioenriched Homoallylic Organoboronic Esters Described %K utility %K silver salt %K Allylation %K Synthesi %K CH %K LiO t Bu %K bi %K Allow %K title compounds %K allylic carbonates %K enantioselective approach %K chiral organoboronates %K Bis %K conversion %K allylation reactions %X Described here is an enantioselective approach of making chiral, β-substituted homoallylic organoboronic esters. In the presence of LiOtBu and a catalytic amount of silver salt, commercial bis­[(pinacolato)­boryl]­methane participated in the iridium-catalyzed asymmetric allylation reactions, delivered a “CH2B­(pin)” group, and yielded the title compounds from allylic carbonates. The synthetic utility of the prepared chiral organoboronates was demonstrated by their conversion to other important classes of compounds. %I ACS Publications