Water-Stable
Anionic Metal–Organic Framework for Highly Selective Separation
of Methane from Natural Gas and Pyrolysis Gas
Lan Li
Xusheng Wang
Jun Liang
Yuanbiao Huang
Hongfang Li
Zujin Lin
Rong Cao
10.1021/acsami.6b00706.s001
https://acs.figshare.com/articles/journal_contribution/Water_Stable_Anionic_Metal_Organic_Framework_for_Highly_Selective_Separation_of_Methane_from_Natural_Gas_and_Pyrolysis_Gas/3159394
A 3D water-stable anionic metal–organic framework
[Zn<sub>4</sub>(hpdia)<sub>2</sub>]·[NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]·3DMF·4H<sub>2</sub>O (<b>FJI-C4</b>) was constructed based on an elaborate phosphorus-containing ligand
5,5′-(hydroxyphosphoryl)diisophthalic acid (H<sub>5</sub>hpdia). <b>FJI-C4</b> with narrow one-dimensional (1D) pore channels exhibits
high selectivity of C<sub>3</sub>H<sub>8</sub>/CH<sub>4</sub> and
C<sub>2</sub>H<sub>2</sub>/CH<sub>4</sub>. It is the first time for
the MOF which contains phosphorus for selective separation of methane
from natural gas and pyrolysis gas.
2016-03-30 00:00:00
Natural Gas
CH 3
NH
DMF
H 5 hpdia
Zn 4
pore channels exhibits
Pyrolysis Gas
pyrolysis gas
Selective Separation
MOF