10.1021/acsami.6b00706.s001
Lan Li
Lan
Li
Xusheng Wang
Xusheng
Wang
Jun Liang
Jun
Liang
Yuanbiao Huang
Yuanbiao
Huang
Hongfang Li
Hongfang
Li
Zujin Lin
Zujin
Lin
Rong Cao
Rong
Cao
Water-Stable
Anionic Metal–Organic Framework for Highly Selective Separation
of Methane from Natural Gas and Pyrolysis Gas
American Chemical Society
2016
Natural Gas
CH 3
NH
DMF
H 5 hpdia
Zn 4
pore channels exhibits
Pyrolysis Gas
pyrolysis gas
Selective Separation
MOF
2016-03-30 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Water_Stable_Anionic_Metal_Organic_Framework_for_Highly_Selective_Separation_of_Methane_from_Natural_Gas_and_Pyrolysis_Gas/3159394
A 3D water-stable anionic metal–organic framework
[Zn<sub>4</sub>(hpdia)<sub>2</sub>]·[NH<sub>2</sub>(CH<sub>3</sub>)<sub>2</sub>]·3DMF·4H<sub>2</sub>O (<b>FJI-C4</b>) was constructed based on an elaborate phosphorus-containing ligand
5,5′-(hydroxyphosphoryl)diisophthalic acid (H<sub>5</sub>hpdia). <b>FJI-C4</b> with narrow one-dimensional (1D) pore channels exhibits
high selectivity of C<sub>3</sub>H<sub>8</sub>/CH<sub>4</sub> and
C<sub>2</sub>H<sub>2</sub>/CH<sub>4</sub>. It is the first time for
the MOF which contains phosphorus for selective separation of methane
from natural gas and pyrolysis gas.