Synthesis of Chiral Coordination Polymers by Spontaneous Resolution Feng Li Taohai Li Xiaoju Li Xing Li Yuling Wang Rong Cao 10.1021/cg0600905.s004 https://acs.figshare.com/articles/dataset/Synthesis_of_Chiral_Coordination_Polymers_by_Spontaneous_Resolution/3077236 Three complexes have been synthesized from the reactions of 3,3-tetramethyleneglutaric acid (H<sub>2</sub>TMG), Cd(NO<sub>3</sub>)<sub>2</sub>, and secondary ligands:  [Cd(TMG)]<i><sub>n</sub></i> (<b>1</b>), {[Cd(TMG)(1,10-phen)·H<sub>2</sub>O]·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>2</b>), and [Cd(TMG)(4,4‘-bipy)]<i><sub>n</sub></i> (<b>3</b>) (phen = 1,10-phenanthroline, 4,4‘-bipy = 4,4‘-bipyridine). By adopting potential chiral ligands, metal−organic helical chains as a transmitter for chiral information, and coordination bonds as chiral discriminative interactions, the chiral coordination polymer <b>3</b> with an interesting three-dimensional architecture has been synthesized successfully by spontaneous resolution. 2006-06-07 00:00:00 Chiral Coordination Polymers chiral ligands 2TMG chiral discriminative interactions chiral information chiral coordination polymer 3 Spontaneous ResolutionThree complexes coordination bonds