Synthesis of Chiral Coordination Polymers by Spontaneous
Resolution
Feng Li
Taohai Li
Xiaoju Li
Xing Li
Yuling Wang
Rong Cao
10.1021/cg0600905.s004
https://acs.figshare.com/articles/dataset/Synthesis_of_Chiral_Coordination_Polymers_by_Spontaneous_Resolution/3077236
Three complexes have been synthesized from the reactions of 3,3-tetramethyleneglutaric acid (H<sub>2</sub>TMG), Cd(NO<sub>3</sub>)<sub>2</sub>,
and secondary ligands: [Cd(TMG)]<i><sub>n</sub></i> (<b>1</b>), {[Cd(TMG)(1,10-phen)·H<sub>2</sub>O]·2H<sub>2</sub>O}<i><sub>n</sub></i> (<b>2</b>), and [Cd(TMG)(4,4‘-bipy)]<i><sub>n</sub></i> (<b>3</b>) (phen = 1,10-phenanthroline, 4,4‘-bipy = 4,4‘-bipyridine). By adopting potential chiral ligands, metal−organic helical chains as a transmitter for
chiral information, and coordination bonds as chiral discriminative interactions, the chiral coordination polymer <b>3</b> with an interesting
three-dimensional architecture has been synthesized successfully by spontaneous resolution.
2006-06-07 00:00:00
Chiral Coordination Polymers
chiral ligands
2TMG
chiral discriminative interactions
chiral information
chiral coordination polymer 3
Spontaneous ResolutionThree complexes
coordination bonds