Aryl Trihydroxyborates: Easily Isolated
Discrete Species Convenient for Direct
Application in Coupling Reactions
Andrew N. Cammidge
Victoria H. M. Goddard
Hemant Gopee
Nicola L. Harrison
David L. Hughes
Christopher J. Schubert
Benjamin M. Sutton
Gary L. Watts
Andrew J. Whitehead
10.1021/ol061564w.s001
https://acs.figshare.com/articles/dataset/Aryl_Trihydroxyborates_Easily_Isolated_Discrete_Species_Convenient_for_Direct_Application_in_Coupling_Reactions/3062479
A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling
processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the
ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the
use of correct reaction stoichiometry.
2006-08-31 00:00:00
Direct Application
Isolated Discrete Species Convenient
reaction stoichiometry
organometallic component
trihydroxyborate salts
arylboron species
borate salts
alternative approach