10.1021/ol061564w.s001 Andrew N. Cammidge Andrew N. Cammidge Victoria H. M. Goddard Victoria H. M. Goddard Hemant Gopee Hemant Gopee Nicola L. Harrison Nicola L. Harrison David L. Hughes David L. Hughes Christopher J. Schubert Christopher J. Schubert Benjamin M. Sutton Benjamin M. Sutton Gary L. Watts Gary L. Watts Andrew J. Whitehead Andrew J. Whitehead Aryl Trihydroxyborates:  Easily Isolated Discrete Species Convenient for Direct Application in Coupling Reactions American Chemical Society 2006 Direct Application Isolated Discrete Species Convenient reaction stoichiometry organometallic component trihydroxyborate salts arylboron species borate salts alternative approach 2006-08-31 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Aryl_Trihydroxyborates_Easily_Isolated_Discrete_Species_Convenient_for_Direct_Application_in_Coupling_Reactions/3062479 A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry.