10.1021/jo0614947.s001
Alexey Y. Koposov
Alexey Y.
Koposov
Rashad R. Karimov
Rashad R.
Karimov
Ivan M. Geraskin
Ivan M.
Geraskin
Victor N. Nemykin
Victor N.
Nemykin
Viktor V. Zhdankin
Viktor V.
Zhdankin
2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and
Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents
American Chemical Society
2006
IO 2 groups
ether
Iodylphenol
microcrystalline products
oxidize sulfides
dimethyldioxirane oxidation
pseudopolymeric arrangements
iodyl
2006-10-27 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/2_Iodylphenol_Ethers_Preparation_X_ray_Crystal_Structure_and_Reactivity_of_New_Hypervalent_Iodine_V_Oxidizing_Reagents/3051277
2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol
ethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysis
of 1-iodyl-2-isopropoxybenzene <b>8c</b> and 1-iodyl-2-butoxybenzene <b>8d</b> revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO<sub>2</sub> groups of different molecules.
2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes
or ketones.