10.1021/jo0614947.s001 Alexey Y. Koposov Alexey Y. Koposov Rashad R. Karimov Rashad R. Karimov Ivan M. Geraskin Ivan M. Geraskin Victor N. Nemykin Victor N. Nemykin Viktor V. Zhdankin Viktor V. Zhdankin 2-Iodylphenol Ethers:  Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents American Chemical Society 2006 IO 2 groups ether Iodylphenol microcrystalline products oxidize sulfides dimethyldioxirane oxidation pseudopolymeric arrangements iodyl 2006-10-27 00:00:00 Dataset https://acs.figshare.com/articles/dataset/2_Iodylphenol_Ethers_Preparation_X_ray_Crystal_Structure_and_Reactivity_of_New_Hypervalent_Iodine_V_Oxidizing_Reagents/3051277 2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol ethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysis of 1-iodyl-2-isopropoxybenzene <b>8c</b> and 1-iodyl-2-butoxybenzene <b>8d</b> revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO<sub>2</sub> groups of different molecules. 2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes or ketones.