%0 Generic
%A Huang, Kexuan
%A Xu, Zhengjiang
%A Li, Yizhi
%A Zheng, Hegen
%D 2007
%T Guest-Induced Helical Metallacyclic Chains in a Porous Coordination Solid
Constructed from a Flexible Ester-Containing Ligand
%U https://acs.figshare.com/articles/dataset/Guest_Induced_Helical_Metallacyclic_Chains_in_a_Porous_Coordination_Solid_Constructed_from_a_Flexible_Ester_Containing_Ligand/3027628
%R 10.1021/cg060667i.s002
%2 https://acs.figshare.com/ndownloader/files/4729996
%K Porous Coordination
%K helical metallacyclic polymer
%K guest THF molecules
%K helical chains
%K THF solution
%K oxygen atoms
%K framework
%K EDPC
%K metallacyclic chains
%X A porous metal−organic framework [Co(SCN)2(EDPC)2(H2O)3]n (1; EDPC = 1,2-ethanediyl di-3-pyridinecarboxylate) has
been synthesized and structurally characterized. Immersing the crystals of 1 in THF solution led to the dynamic framework of 1 undergoing
a crystal-to-crystal guest-exchange process to afford the helical metallacyclic polymer [Co(SCN)2(EDPC)2(THF)]n [1⊃THF]. The guest
THF molecules were accommodated in the cavities of the metallacyclic chains and showed the handness of the helical chains by their
oxygen atoms as probes.
%I ACS Publications