10.1021/ic0616434.s001
Banglin Chen
Banglin
Chen
Shengqian Ma
Shengqian
Ma
Fatima Zapata
Fatima
Zapata
Frank R. Fronczek
Frank R.
Fronczek
Emil B. Lobkovsky
Emil B.
Lobkovsky
Hong-Cai Zhou
Hong-Cai
Zhou
Rationally Designed Micropores within a Metal−Organic Framework for
Selective Sorption of Gas Molecules
American Chemical Society
2007
pore cavities
framework interpenetration
Selective Sorption
Bpe
FMA
gas molecules
sorption behaviors
pore windows
MOF
2007-02-19 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Rationally_Designed_Micropores_within_a_Metal_Organic_Framework_for_Selective_Sorption_of_Gas_Molecules/3025531
A microporous metal−organic framework, MOF, Cu(FMA)(4,4'-Bpe)<sub>0.5</sub> (<b>3a</b>, FMA = fumarate; 4,4'-Bpe = 4,4’-Bpe
= <i>trans</i>-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double
framework interpenetration. With pore cavities of about 3.6 Å, which are interconnected by pore windows of 2.0 ×
3.2 Å, <b>3a</b> shows highly selective sorption behaviors of gas molecules.