Novel 3D Ln<sup>III</sup>−Cu<sup>I</sup> Supramolecular Architecture Based on 2D MOFs with
(6,3) Topology
Feng-Qin Wang
Xiang-Jun Zheng
Yong-Hong Wan
Chang-Yan Sun
Zhe-Ming Wang
Ke-Zhi Wang
Lin-Pei Jin
10.1021/ic062236v.s005
https://acs.figshare.com/articles/dataset/Novel_3D_Ln_sup_III_sup_Cu_sup_I_sup_Supramolecular_Architecture_Based_on_2D_MOFs_with_6_3_Topology/3012502
Three novel coordination polymers, [LnCu(PZDC)<sub>3</sub>]·[Ln(H<sub>2</sub>O)<sub>9</sub>]<sub>0.5</sub>·[(H<sub>2</sub>O)<sub>7</sub>H<sup>+</sup>]<sub>0.5</sub> [Ln = La (<b>1</b>), Eu (<b>2</b>), Gd (<b>3</b>)], were synthesized. They
are the first 3d−4f heterometallic framework with supramolecular
1D channels, in which lanthanide hydrate cations and lattice water
molecules are located.
2007-04-16 00:00:00
Ln
0.5
Supramolecular Architecture
III
lanthanide hydrate cations
7 H
2 D MOFs
lattice water molecules
supramolecular 1 D channels
novel coordination polymers