Novel 3D Ln<sup>III</sup>−Cu<sup>I</sup> Supramolecular Architecture Based on 2D MOFs with (6,3) Topology Feng-Qin Wang Xiang-Jun Zheng Yong-Hong Wan Chang-Yan Sun Zhe-Ming Wang Ke-Zhi Wang Lin-Pei Jin 10.1021/ic062236v.s005 https://acs.figshare.com/articles/dataset/Novel_3D_Ln_sup_III_sup_Cu_sup_I_sup_Supramolecular_Architecture_Based_on_2D_MOFs_with_6_3_Topology/3012502 Three novel coordination polymers, [LnCu(PZDC)<sub>3</sub>]·[Ln(H<sub>2</sub>O)<sub>9</sub>]<sub>0.5</sub>·[(H<sub>2</sub>O)<sub>7</sub>H<sup>+</sup>]<sub>0.5</sub> [Ln = La (<b>1</b>), Eu (<b>2</b>), Gd (<b>3</b>)], were synthesized. They are the first 3d−4f heterometallic framework with supramolecular 1D channels, in which lanthanide hydrate cations and lattice water molecules are located. 2007-04-16 00:00:00 Ln 0.5 Supramolecular Architecture III lanthanide hydrate cations 7 H 2 D MOFs lattice water molecules supramolecular 1 D channels novel coordination polymers