%0 Generic %A Moussa, J. %A Guyard-Duhayon, C. %A Boubekeur, K. %A Amouri, H. %A Yip, S.-K. %A W. W. Yam, V. %D 2007 %T Self-Assembly of One- and Two-Dimensional Coordination Polymers with Quinonoid Backbones Featuring Coinage Metals as Nodes %U https://acs.figshare.com/articles/dataset/Self_Assembly_of_One_and_Two_Dimensional_Coordination_Polymers_with_Quinonoid_Backbones_Featuring_Coinage_Metals_as_Nodes/3009592 %R 10.1021/cg060944l.s003 %2 https://acs.figshare.com/ndownloader/files/4710904 %K novel supramolecular %K NodesWe report %K organometallic linker %K Quinonoid Backbones Featuring Coinage Metals %K 2 D %K 3.638 Å %K zigzag chain %K 1 D chain neighbors %K Cu %X We report the use of the organometallic linker [Cp*Ir(η4-benzoquinone)] (1b) LIr to construct novel supramolecular one- and two-dimensional (1D and 2D) coordination polymers {[Cu2(LIr)2(CH3CN)(OTf)2][LIr](OTf)}n (3) and {[Ag2(CH3CN)2][LIr]2(OTf)2}n (4). Complex 3 formed a zigzag chain of Cu(I) and Cu(II) centers connected through irido-quinonoid backbones, while complex 4 exhibited argentopilic Ag---Ag d10---d10 contacts at d = 3.638 Å and C---H/π interactions between the 1D chain neighbors. %I ACS Publications