%0 Generic
%A Moussa, J.
%A Guyard-Duhayon, C.
%A Boubekeur, K.
%A Amouri, H.
%A Yip, S.-K.
%A W. W. Yam, V.
%D 2007
%T Self-Assembly of One- and Two-Dimensional Coordination Polymers
with Quinonoid Backbones Featuring Coinage Metals as Nodes
%U https://acs.figshare.com/articles/dataset/Self_Assembly_of_One_and_Two_Dimensional_Coordination_Polymers_with_Quinonoid_Backbones_Featuring_Coinage_Metals_as_Nodes/3009592
%R 10.1021/cg060944l.s003
%2 https://acs.figshare.com/ndownloader/files/4710904
%K novel supramolecular
%K NodesWe report
%K organometallic linker
%K Quinonoid Backbones Featuring Coinage Metals
%K 2 D
%K 3.638 Å
%K zigzag chain
%K 1 D chain neighbors
%K Cu
%X We report the use of the organometallic linker [Cp*Ir(η4-benzoquinone)] (1b) LIr to construct novel supramolecular
one- and two-dimensional (1D and 2D) coordination polymers {[Cu2(LIr)2(CH3CN)(OTf)2][LIr](OTf)}n (3) and {[Ag2(CH3CN)2][LIr]2(OTf)2}n (4). Complex 3 formed a zigzag chain of Cu(I) and Cu(II) centers connected through irido-quinonoid backbones,
while complex 4 exhibited argentopilic Ag---Ag d10---d10 contacts at d = 3.638 Å and C---H/π interactions between the 1D chain
neighbors.
%I ACS Publications