10.1021/cg060944l.s003
J. Moussa
J.
Moussa
C. Guyard-Duhayon
C.
Guyard-Duhayon
K. Boubekeur
K.
Boubekeur
H. Amouri
H.
Amouri
S.-K. Yip
S.-K.
Yip
V. W. W. Yam
V.
W. W. Yam
Self-Assembly of One- and Two-Dimensional Coordination Polymers
with Quinonoid Backbones Featuring Coinage Metals as Nodes
American Chemical Society
2007
novel supramolecular
NodesWe report
organometallic linker
Quinonoid Backbones Featuring Coinage Metals
2 D
3.638 Å
zigzag chain
1 D chain neighbors
Cu
2007-05-02 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Self_Assembly_of_One_and_Two_Dimensional_Coordination_Polymers_with_Quinonoid_Backbones_Featuring_Coinage_Metals_as_Nodes/3009592
We report the use of the organometallic linker [Cp*Ir(η<sup>4</sup>-benzoquinone)] (<b>1b</b>) L<sup>Ir</sup> to construct novel supramolecular
one- and two-dimensional (1D and 2D) coordination polymers {[Cu<sub>2</sub>(L<sup>Ir</sup>)<sub>2</sub>(CH<sub>3</sub>CN)(OTf)<sub>2</sub>][L<sup>Ir</sup>](OTf)}<i><sub>n</sub></i> (<b>3</b>) and {[Ag<sub>2</sub>(CH<sub>3</sub>CN)<sub>2</sub>][L<sup>Ir</sup>]<sub>2</sub>(OTf)<sub>2</sub>}<i><sub>n</sub></i> (<b>4</b>). Complex <b>3</b> formed a zigzag chain of Cu(I) and Cu(II) centers connected through irido-quinonoid backbones,
while complex <b>4</b> exhibited argentopilic Ag---Ag d<sup>10</sup>---d<sup>10</sup> contacts at <i>d</i> = 3.638 Å and C---H/π interactions between the 1D chain
neighbors.