jo0614947_si_001.cif (16.77 kB)
2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents
dataset
posted on 2006-10-27, 00:00 authored by Alexey Y. Koposov, Rashad R. Karimov, Ivan M. Geraskin, Victor N. Nemykin, Viktor V. Zhdankin2-Iodylphenol ethers were prepared by the dimethyldioxirane oxidation of the corresponding 2-iodophenol
ethers and isolated as chemically stable, microcrystalline products. Single-crystal X-ray diffraction analysis
of 1-iodyl-2-isopropoxybenzene 8c and 1-iodyl-2-butoxybenzene 8d revealed pseudopolymeric arrangements in the solid state formed by intermolecular interactions between IO2 groups of different molecules.
2-Iodylphenol ethers can selectively oxidize sulfides to sulfoxides and alcohols to the respective aldehydes
or ketones.