10.1021/ol0713032.s006
Florin M. Istrate
Florin M.
Istrate
Fabien Gagosz
Fabien
Gagosz
Synthesis of Functionalized Pyrroles via
Gold(I)-Catalyzed aza-Claisen-Type
Rearrangement
American Chemical Society
2007
pentenynyl allyl tosylamides
quaternary centers
selectivity
functionalized pyrroles
RearrangementGold
cyclization
mechanism
construction
formation
Functionalized Pyrroles
Synthesi
2007-08-02 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Synthesis_of_Functionalized_Pyrroles_via_Gold_I_Catalyzed_aza_Claisen_Type_Rearrangement/2993254
Gold(I)-catalyzed cyclization of pentenynyl allyl tosylamides allows the rapid construction of functionalized pyrroles. The concerted aza-Claisen-type mechanism induces a complete selectivity of the process and allows the easy formation of quaternary centers.