%0 Generic
%A Au-Yeung, Ho Yu
%A Lam, Chung Hei
%A Lam, Chi-Keung
%A Wong, Wai-Yeung
%A Lee, Hung Kay
%D 2007
%T Unusual Iron(II) and Cobalt(II) Complexes Derived from Monodentate
Arylamido Ligands#
%U https://acs.figshare.com/articles/dataset/Unusual_Iron_II_and_Cobalt_II_Complexes_Derived_from_Monodentate_Arylamido_Ligands_sup_sup_/2985265
%R 10.1021/ic700850e.s011
%2 https://acs.figshare.com/ndownloader/files/4685917
%K THF
%K coordination chemistry
%K Co II ions
%K Fe II
%K monoamido complexes
%K CH 2 Bu t
%K SiMe 3
%K Pr i
%K Monodentate Arylamido Ligands
%X The coordination chemistry of the N-substituted arylamido ligands
[N(R)(C6H3R‘2-2,6)] [R = SiMe3, R‘ = Me (L1); R = CH2But, R‘
= Pri (L2)] toward FeII and CoII ions was studied. The monoamido
complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily
with MeLi, affording the mononuclear, paramagnetic iron(II) and
cobalt(II) methyl−arylamido complexes [M(L1)(Me)(tmeda)] [M =
Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the
unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5).
%I ACS Publications