%0 Generic %A Au-Yeung, Ho Yu %A Lam, Chung Hei %A Lam, Chi-Keung %A Wong, Wai-Yeung %A Lee, Hung Kay %D 2007 %T Unusual Iron(II) and Cobalt(II) Complexes Derived from Monodentate Arylamido Ligands# %U https://acs.figshare.com/articles/dataset/Unusual_Iron_II_and_Cobalt_II_Complexes_Derived_from_Monodentate_Arylamido_Ligands_sup_sup_/2985265 %R 10.1021/ic700850e.s011 %2 https://acs.figshare.com/ndownloader/files/4685917 %K THF %K coordination chemistry %K Co II ions %K Fe II %K monoamido complexes %K CH 2 Bu t %K SiMe 3 %K Pr i %K Monodentate Arylamido Ligands %X The coordination chemistry of the N-substituted arylamido ligands [N(R)(C6H3R‘2-2,6)] [R = SiMe3, R‘ = Me (L1); R = CH2But, R‘ = Pri (L2)] toward FeII and CoII ions was studied. The monoamido complexes [M(L1)(Cl)(tmeda)] [M = Fe (1), Co (2)] react readily with MeLi, affording the mononuclear, paramagnetic iron(II) and cobalt(II) methyl−arylamido complexes [M(L1)(Me)(tmeda)] [M = Fe (3), Co (4)]. Treatment of 2:1 [Li(L2)(THF)2]/FeCl2 affords the unusual two-coordinate iron(II) bis(arylamide) [Fe(L2)2] (5). %I ACS Publications