Spectroelectrochemistry and DFT Analysis of a New {RuNO}<i><sup>n</sup></i><sup></sup> Redox
System with Multifrequency EPR Suggesting Conformational Isomerism
in the {RuNO}<sup>7</sup> State
Priti Singh
Jan Fiedler
Stanislav Záliš
Carole Duboc
Mark Niemeyer
Falk Lissner
Thomas Schleid
Wolfgang Kaim
10.1021/ic701206a.s008
https://acs.figshare.com/articles/dataset/Spectroelectrochemistry_and_DFT_Analysis_of_a_New_RuNO_i_sup_n_sup_i_sup_sup_Redox_System_with_Multifrequency_EPR_Suggesting_Conformational_Isomerism_in_the_RuNO_sup_7_sup_State/2978209
The compound [Ru(NO)(bpym)(terpy)](PF<sub>6</sub>)<sub>3</sub>, bpym = 2,2‘-bipyrimidine and terpy = 2,2‘:6‘,2‘ ‘-terpyridine, with a
{RuNO}<sup>6</sup> configuration (angle Ru−N−O 175.2(4)°) was obtained from the structurally characterized precursor [Ru(NO<sub>2</sub>)(bpym)(terpy)](PF<sub>6</sub>), which shows bpym-centered reduction and metal-centered oxidation, as evident from
EPR spectroscopy. The relatively labile [Ru(NO)(bpym)(terpy)]<sup>3+</sup>, which forms a structurally characterized acetonitrile
substitution product [Ru(CH<sub>3</sub>CN)(bpym)(terpy)](PF<sub>6</sub>)<sub>2</sub> upon treatment with CH<sub>3</sub>OH/CH<sub>3</sub>CN, is electrochemically reduced
in three one-electron steps of which the third, leading to neutral [Ru(NO)(bpym)(terpy)], involves electrode adsorption.
The first-two reduction processes cause shifts of ν(NO) from 1957 via 1665 to 1388 cm<sup>-1</sup>, implying a predominantly
NO-centered electron addition. UV−vis-NIR Spectroscopy shows long-wavelength ligand-to-ligand charge transfer
absorptions for [Ru<sup>II</sup>(NO<sup>-I</sup>)(bpym)(terpy)]<sup>+</sup> in the visible region, whereas the paramagnetic intermediate [Ru(NO)(bpym)(terpy)]<sup>2+</sup> exhibits no distinct absorption maximum above 309 nm. EPR spectroscopy of the latter at 9.5, 95,
and 190 GHz shows the typical invariant pattern of the {RuNO}<sup>7</sup> configuration; however, the high-frequency
measurements at 4 and 10 K reveal a splitting of the <i>g</i><sub>1</sub> and <i>g</i><sub>2</sub> components, which is tentatively attributed to
conformers resulting from the bending of RuNO. DFT calculations support the assignments of oxidation states and
the general interpretation of the electronic structure.
2007-10-29 00:00:00
Ru
bpym
g 2 components
OH
EPR spectroscopy
DFT calculations support
acetonitrile substitution product
UV
RuNO
n Redox System
CH
CN
Multifrequency EPR Suggesting Conformational Isomerism
II